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文獻名：Study of sodium lignosulfonate prepare low-rank coal-water slurry: Experiments and simulations

 

 

作者： Lin Li¹， Chuandong Ma¹²， Mengyu Lin¹²， Mingpu Liu¹， Hao Yu¹， Qingbiao Wang³⁴， Xiaoqiang Cao²， Xiaofang You¹

¹ School of Chemistry and Biological Engineering, Shandong University of Science and Technology, Qingdao 266590, China

² College of Safety and Environment Engineering, Shandong University of Science and Technology, Qingdao 266590, China

³ National Engineering Laboratory for Coalmine Backfilling Mining, Shandong University of Science and Technology, Tai'an 271019, China

⁴ Department of Resource and Civil Engineering, Shandong University of Science and Technology, Tai'an 271019, China

 

 

摘要：The effect of sodium lignosulfonate (SL) as additive on the preparation of low-rank coal-water slurry (LCWS) was studied by experiments and molecular dynamics (MD) simulations. The experimental results show that the appropriate amount of additives is beneficial to reduce the viscosity of LCWS and increase the slurry concentration. Adsorption isotherm studies showed that SL conforms to single-layer adsorption on the coal surface, and ? G_ads⁰ was negative, proving that the reaction was spontaneous. Zeta potential measurements showed that SL increased the negative charge on coal. FTIR scanning and XPS wide-range scanning were performed on the coal before and after adsorption, and it was found that the content of oxygen functional groups on coal increased after adsorption. Simulation results show that when a large number of SL molecules exist in the solution, some SL molecules will bind to hydrophobic hydrocarbon groups on coal. The rest of the SL molecules, their hydrophobic alkyl tails, come into contact with each other and aggregate in solution. The agglomeration of SL molecules and the surface of coal with static electricity will also produce electrostatic interaction, which is conducive to the even dispersion of coal particles. The results of mean square displacement (MSD) and self-diffusion coefficient (D) show that the addition of SL reduces the diffusion rate of water molecules. Simulation results correspond to experimental results, indicating that MD simulation is accurate and feasible.

 

關鍵詞：LCWS； Low-rank coal； Sodium lignosulfonate； MD simulation