国产日产欧美精品-亚洲国产综合久久精品-色综合色国产热无码一-亚洲欧美日本国产,免费观看一区二区三区_在线观看片A免费不卡观看_亚洲а∨天堂久久精品_99久无码中文字幕一本久道

作者： Huang Tang,^a  Zhewei Gu,^a  Cheng Li,^a  Zhibo Li,^b  Wei Wu^a  and  Xiqun Jiang*^a

aMOE Key Laboratory of High Performance Polymer Materials and Technology, and Department of Polymer Science & Engineering, College of Chemistry & Chemical Engineering, Nanjing University, Nanjing, China

bSchool of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao, China

 

摘要：A new approach to the development of functional biomaterials is to obtain a controllable nanostructure through supramolecular self-assembly. Although much effort has been devoted to supramolecular structures with different morphologies and properties, fluorescent macrocycle-based carbon material assembly into three-dimensional vesicle morphologies remains a challenge. Herein, the supramolecular properties of cycloparaphenylene (CPP) in a mixed solution are characterized and controlled successfully through the regulation of different concentrations and solvent ratios. The self-assembled CPP molecules form a three-dimensional hollow structure in different solutions. The assembled vesicle structure endows CPPs with cell biology application and it is found that CPPs could be internalized by cells via an energy- or temperature-independent mechanism. Even in the presence of different inhibitors, cellular uptake of [10]CPP could not be affected. These supramolecular and biological findings of CPPs extend the current understanding of cycloparaphenylene chemistry and will open up new and more attractive applications in nanotechnology, biology and materials science.